A study of the metal complexing of naphthalene-2,3-crown ethers using fluorescence spectroscopy: Part III

Yapar G., ERK C.

DYES AND PIGMENTS, vol.48, no.3, pp.173-177, 2001 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 48 Issue: 3
  • Publication Date: 2001
  • Doi Number: 10.1016/s0143-7208(00)00101-7
  • Journal Name: DYES AND PIGMENTS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.173-177
  • Istanbul Technical University Affiliated: Yes

Abstract

2,3-Dioxanaphthalene derivatives of [3n]crown-n macrocycles were synthesised from 2,3-dihydroxynaphthalene and polyglycoldihalides and studied for their cationic recognition properties using steady state fluorescence spectroscopy. The association constants for the interaction of 2,3-naphthol[12]crown-4, 2,3-naphtho[15]crown-5 and 2,3-naphtho[18]crown-6 with LiClO4, NaClO4, NaSCN, and KSCN were measured in acetonitrile. Excellent correlation of spectroscopic, cationic charge-radii and macrocycle backbone size data was found. (C) 2001 Elsevier Science Ltd. All rights reserved.