Non-peripherally tetrasubstituted phthalocyanines: Synthesis, characterization and, photophysical investigation


TUNCER S., Kaya K. , Özçeşmeci İ. , Burat A. K.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.827, ss.78-85, 2017 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 827
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.jorganchem.2016.11.008
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Sayfa Sayıları: ss.78-85

Özet

The synthesis, characterization and photophysical properties of novel, non-peripherally tetrasubstituted metal-free and metallophthalocyanines (MPcs) (Zn, In) bearing morpholinoethoxy groups have been reported. The new compounds were characterized by using elemental analysis, H-1 NMR, UV-Vis and FTIR spectroscopy and mass spectrometry. The aggregative properties of the novel compounds were investigated in different concentrations. General trends for fluorescence quantum yields and lifetimes of metal-free and metallophthalocyanines were also described in tetrahydrofuran (THF). The fluorescence of these compounds is effectively quenched by 1,4-benzoquinone (BQ) in THF. (C) 2016 Elsevier B.V. All rights reserved.