Lithium ion batteries which are an energy storage system have increasing attention owing to suitability and advantages for many applications. Although it has ideal specifications, the capacity properties still have to be developed. In this study, the electrical conductivity of the anode was increased by using a conductive polymer binder and the active material content of the anode was also enhanced without adding carbon additives. Silicon based anodes were manufactured by using poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT:PSS) and poly(3,4-ethylenedioxythiophene)/polythiophenesulfonyl chloride (PEDOT:PTS) conductive polymer binders. Si/PEDOT:PTS anode showed about 2000 mAh/g specific capacities after 60 cycles with decreasing impedance.