Crosslinking Copolymerization of Vinyl Monomers Using Non-Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone)

Ince A., Bicak N.

15th International Conference on Polymers and Organic Chemistry (POC), Timisoara, Romanya, 10 - 13 Haziran 2014, cilt.352, ss.38-41 identifier identifier

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Cilt numarası: 352
  • Doi Numarası: 10.1002/masy.201400149
  • Basıldığı Şehir: Timisoara
  • Basıldığı Ülke: Romanya
  • Sayfa Sayıları: ss.38-41
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Morpholine substituted poly(vinyl methyl ketone) (MSP) is presented as non-vinyl crosslinker forming insoluble polymers in polymerization of vinyl monomers. In this process, crosslinking occurs via double bonds in situ formed by thermal de-amination of MSP above 70 degrees C as demonstrated in polymerization of methylmethacrylate (MMA), styrene and 4-vinyl pyridine (4-VP) monomers.