Synthesis, Structural Characterization, Spectroscopic and Electrochemical Studies of N,N '-bis[(2,4-dimethoxyphenyl) methylidene]butane-1,4-diamine

Dolaz M., McKee V., Gölcü A., Tumer M.

CURRENT ORGANIC CHEMISTRY, cilt.14, sa.3, ss.281-288, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 14 Sayı: 3
  • Basım Tarihi: 2010
  • Doi Numarası: 10.2174/138527210790231946
  • Dergi Adı: CURRENT ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.281-288
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

In this study, the title compound, N,N'-bis[(2,4-dimethoxyphenyl)methylidene]butane-1,4-diamine (L), was prepared and characterized by analytical and spectroscopic methods. The analytical data of the Schiff base ligand (L) confirms the proposed structure. The conductance value indicates that the ligand is non-electrolyte. The electrochemical properties of the ligand (L) are dependent on irreversible and quasi-reversible redox waves in the anodic and cathodic regions, due to oxidation and reduction. The single crystal of the ligand (L) was obtained from MeOH solution. Space group and crystal system of the ligand are P2(1)/(C) and monoclinic, respectively. Unit cell dimensions of the ligand are a = 4.0647(2) angstrom, b = 17.4186 (10) angstrom, c = 13.8982(8) angstrom and beta = 94.325 (1)degrees.