Synthesis of new metal-free and metal-containing phthalocyanines with tertiary or quaternary aminoethyl substituents

Gursoy S., CIHAN A., Kocak M., BEKAROGLU O.

MONATSHEFTE FUR CHEMIE, vol.132, no.7, pp.813-819, 2001 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 132 Issue: 7
  • Publication Date: 2001
  • Doi Number: 10.1007/s007060170068
  • Journal Name: MONATSHEFTE FUR CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.813-819
  • Istanbul Technical University Affiliated: Yes

Abstract

A novel phthalodinitrile derivative carrying dimethylatrunoethylsulfanyl groups at positions 4 and 5 was synthesized from 2-dimethylaminoethanethiol hydrochloride and 1,2-dichloro-4,5-dicyanobenzene. Its cyclotetramerization in the presence of 2-dimethylamino-ethanol or metal salts (CoCl2, Zn(OAc)(2)) gave metal-free or metal-containing phthalocyanines (M = Co or Zn). These phthalocyanines were converted into water soluble quaternized products by reaction with methyl iodide. The new compounds were characterized by elemental analysis, IR, NMR, and electronic spectra.