Observations on the copper(II) catalyzed reactions of enaminones and dimethyl diazomalonate


Gungor F. S. , Anac O. , SEZER O.

TETRAHEDRON LETTERS, cilt.48, ss.4883-4886, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 48 Konu: 28
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.tetlet.2007.05.063
  • Dergi Adı: TETRAHEDRON LETTERS
  • Sayfa Sayıları: ss.4883-4886

Özet

The Cu(acaC)(2) catalyzed reactions of dimethyl diazomalonate with enaminones yielded 1,5-cyclization and alpha-CH insertion products. In the case of anilino derivatives (R-1 or R-2 = Ph), products resulting from an unusual insertion to the benzoyl ring dominated the reaction. (c) 2007 Elsevier Ltd. All rights reserved.