Metal-containing phthalocyanines substituted with one branched bulky moiety and six alkylthio groups

Bayir Z., MEREY S., HAMURYUDAN E.

MONATSHEFTE FUR CHEMIE, cilt.134, sa.7, ss.1027-1031, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 134 Sayı: 7
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1007/s00706-003-0004-6
  • Dergi Adı: MONATSHEFTE FUR CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1027-1031
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Unsymmetrically substituted metal-phthalocyanines composed of three hexylthio groups and one 1-chloro-3,4-dicyano-6-[2-(2-pyridylmethylamino)phenylthio]benzene moiety was prepared by cyclization of the reactants in the presence of the anhydrous metal salts Zn(CH3COO)(2), NiCl2, and CoCl2. The new unsymmetric phthalocyanines are very soluble in common organic solvents. The compounds were characterised by their elemental analyses, IR, H-1 NMR, MS and UV/Vis spectra.