Metal-containing phthalocyanines substituted with one branched bulky moiety and six alkylthio groups


Bayir Z. , MEREY S., HAMURYUDAN E.

MONATSHEFTE FUR CHEMIE, cilt.134, ss.1027-1031, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 134 Konu: 7
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1007/s00706-003-0004-6
  • Dergi Adı: MONATSHEFTE FUR CHEMIE
  • Sayfa Sayıları: ss.1027-1031

Özet

Unsymmetrically substituted metal-phthalocyanines composed of three hexylthio groups and one 1-chloro-3,4-dicyano-6-[2-(2-pyridylmethylamino)phenylthio]benzene moiety was prepared by cyclization of the reactants in the presence of the anhydrous metal salts Zn(CH3COO)(2), NiCl2, and CoCl2. The new unsymmetric phthalocyanines are very soluble in common organic solvents. The compounds were characterised by their elemental analyses, IR, H-1 NMR, MS and UV/Vis spectra.