Determination of Lead in Water Samples by GFAAS after Collection on Montmorillonite with Slurry Introduction

Calıskan E., Tınas H., Ozbek N., Akman S.

ANALYTICAL SCIENCES, cilt.33, sa.3, ss.387-390, 2017 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 3
  • Basım Tarihi: 2017
  • Doi Numarası: 10.2116/analsci.33.387
  • Dergi Adı: ANALYTICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.387-390
  • Anahtar Kelimeler: Separation, Pb, graphite furnace atomic absorption spectrometry, slurry sampling, montmorillonite, SOLID-PHASE EXTRACTION, ATOMIC-ABSORPTION-SPECTROMETRY, CADMIUM, ADSORPTION, IONS, INJECTION, SORBENTS, PB(II), COPPER, ETAAS
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

In this study, a highly accurate, fast and practical separation/enrichment technique is described to determine the Pb in tap water samples by graphite furnace atomic absorption spectrometry. For this purpose, at first, Pb was collected on montmorillonite by batch technique, the supernatant was decanted and the solid phase was slurried in a mixture of 0.1% Triton X-114 and 0.1 mol L-1 HNO3 then directly introduced into graphite furnace without elution. Since the elution step was not applied, the method was simpler and faster compared to conventional techniques. The risks of elution step on the precision and recovery were eliminated. Up to 50-fold enrichment could be obtained by this method. The limit of detection (3 delta, N = 10) and characteristic concentration of the method for Pb were 0.46 and 1.13 mu g L-1, respectively. In addition, the Pb in water samples (tap and river) collected from different regions of Turkey were determined.