Synthesis, characterization and redox properties of a new vic-dioxime and its transition metal complexes


Tas E. F. , ULUSOY M., GULER M., Yilmaz I.

TRANSITION METAL CHEMISTRY, cilt.29, ss.180-184, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

Özet

A novel vic-dioxime, 1,2 dihydroxyimino-1-p-tolyl-3-aza-6-morpholine heptane (LH2) was prepared by reacting anti-p-tolylchloroglyoxime with 4-(3-aminopropyl) morpholine in absolute THF. Mononuclear complexes with a metal-ligand ratio of 1:2 were prepared using Co-II, Cu-II and Ni-II salts. The ligand and its complexes were characterized by elemental analyses, FT-IR, u.v.-vis., H-1- and C-13-n.m.r. spectra, magnetic susceptibility measurements, thermogravimetric analyses (t.g.a.), and by cyclic voltammetry.