New phthalocyanines bearing tetra(hydroxyethylthio) functionalities


Ozcesmeci I. , OKUR A. I. , GUL A.

DYES AND PIGMENTS, cilt.75, ss.761-765, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 75 Konu: 3
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.dyepig.2006.08.003
  • Dergi Adı: DYES AND PIGMENTS
  • Sayfa Sayıları: ss.761-765

Özet

Zn(II), Co(II), Ni(II) and metal-free phthalocyanines (2-5) beating a hydroxyethylthio substituent on each benzo group were prepared from 4-(hydroxyethylthio)phthalonitrile (1) and the corresponding divalent metal salt. The reactivity of the hydroxyethyl groups was demonstrated by esterification of phthalocyanine, derivatives (2-5) with acetic anhydride at reflux temperature and acetylated phthalocyanine compounds (6-9) were obtained. The new compounds have been characterized by elemental analyses, IR, UV-vis, mass and H-1 NMR spectroscopy. (c) 2006 Elsevier Ltd. All rights reserved.