New phthalocyanines bearing tetra(hydroxyethylthio) functionalities

Ozcesmeci I., OKUR A. I., GUL A.

DYES AND PIGMENTS, cilt.75, sa.3, ss.761-765, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 75 Sayı: 3
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.dyepig.2006.08.003
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.761-765
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Zn(II), Co(II), Ni(II) and metal-free phthalocyanines (2-5) beating a hydroxyethylthio substituent on each benzo group were prepared from 4-(hydroxyethylthio)phthalonitrile (1) and the corresponding divalent metal salt. The reactivity of the hydroxyethyl groups was demonstrated by esterification of phthalocyanine, derivatives (2-5) with acetic anhydride at reflux temperature and acetylated phthalocyanine compounds (6-9) were obtained. The new compounds have been characterized by elemental analyses, IR, UV-vis, mass and H-1 NMR spectroscopy. (c) 2006 Elsevier Ltd. All rights reserved.