Reactions of alpha,beta-enones with diazo compounds .2. Synthesis of dihydrofuran derivatives


Anac O., Daut A.

LIEBIGS ANNALEN-RECUEIL, sa.6, ss.1249-1254, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Konu: 6
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1002/jlac.199719970630
  • Dergi Adı: LIEBIGS ANNALEN-RECUEIL
  • Sayfa Sayıları: ss.1249-1254

Özet

Several alpha,beta-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetyl-acetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.