POLYMERIZATION OF ACRYLAMIDE BY ELECTROLYTICALLY GENERATED CE(IV)-ORGANIC ACID REDOX SYSTEMS

SARAC A., BASAK H., SOYDAN A., AKAR A.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.198, ss.191-198, 1992 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 198
  • Basım Tarihi: 1992
  • Doi Numarası: 10.1002/apmc.1992.051980116
  • Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.191-198
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

Ce(IV) salt-malonic acid or citric acid initiator systems were used for the polymerization of acrylamide in the presence of electrolysis. This allowed Ce(III) to be converted to Ce(IV) during polymerization. Graphite, silver, chromium/nickel, lead, platinum and stainless-steel electrodes were used. The highest polymerization yield was obtained with a stainless-steel electrode.