POLYMERIZATION OF ACRYLAMIDE BY ELECTROLYTICALLY GENERATED CE(IV)-ORGANIC ACID REDOX SYSTEMS


SARAC A., BASAK H., SOYDAN A., AKAR A.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.198, ss.191-198, 1992 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 198
  • Basım Tarihi: 1992
  • Doi Numarası: 10.1002/apmc.1992.051980116
  • Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Sayfa Sayıları: ss.191-198

Özet

Ce(IV) salt-malonic acid or citric acid initiator systems were used for the polymerization of acrylamide in the presence of electrolysis. This allowed Ce(III) to be converted to Ce(IV) during polymerization. Graphite, silver, chromium/nickel, lead, platinum and stainless-steel electrodes were used. The highest polymerization yield was obtained with a stainless-steel electrode.