Effective TiO2 supported Cu-Complex catalyst in NaBH4 hydrolysis reaction to hydrogen generation

Kilinc D., Sahin Ö.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, cilt.44, sa.34, ss.18858-18865, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 34
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.ijhydene.2018.12.225
  • Dergi Adı: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.18858-18865
  • Anahtar Kelimeler: Cu-complex, Catalyst, Schiff base, Hydrolysis, NaBH4, SODIUM-BOROHYDRIDE, HETEROGENEOUS CATALYST, REUSABLE CATALYST, STORAGE MATERIALS, H-2 PRODUCTION, IONIC LIQUID, LOW-COST, REGENERATION, HYDRIDES, NANOPARTICLES
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

This paper reports the experimental results on using TiO2 based Cu(II)-Schiff Base complex catalyst for hydrolysis of NaBH4. In the presence of Cu-Schiff Base complex which we reported in advance [1] and with titanium dioxide supports a novel catalyst named TiO2 supported 4-4'-Methylenbis (2,6-diethyl)aniline-3,5-di-tert-buthylsalisylaldimine-Cu complex is prepared, successfully. The synthesized catalyst was characterized by means of X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Brunauer-Emmett-Teller Surface Area Analysis (BET) and Fourier Transform Infrared Spectroscopy (FT-IR). The as prepared catalyst was employed to generate hydrogen through hydrolysis reaction of NaBH4. Effects of different parameters (e.g. amount of Cu-Schiff Base complex in all catalyst, percentage of NaBH4, percentage of NaOH, amount of TiO2 supported Cu-Schiff Base complex catalyst and different temperatures) are also investigated. A high apparent activation energy (Ea), 25,196 kJ.mol(-)1 is calculated for hydrolysis of NaBH4 at 20-50 degrees C. Hydrogen generation rate was 14,020 mL H-2/g(cat).min and 22,071 mL H-2/g(cat).min in order of 30 degrees C and 50 degrees C. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.