Effect of cationic polymer on the separation of phenols by capillary electrophoresis

Erim F. B.

JOURNAL OF CHROMATOGRAPHY A, vol.768, no.1, pp.161-167, 1997 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 768 Issue: 1
  • Publication Date: 1997
  • Journal Name: JOURNAL OF CHROMATOGRAPHY A
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.161-167
  • Keywords: buffer composition, phenols, chlorophenols, nitrophenols, polyethyleneimine, EXCHANGE ELECTROKINETIC CHROMATOGRAPHY, MICELLAR SOLUTIONS, OPTIMIZATION, ANIONS
  • Istanbul Technical University Affiliated: Yes

Abstract

The capillary electrophoretic separation of substituted phenols was examined using high-molecular-mass polyethyleneimine (PEI) as a buffer additive. The added PEI to the running buffer showed a strong interaction with the phenols and affected the electrophoretic mobilities and migration order of phenols. The influence of pH, organic solvent and concentration of polyelectrolyte on the electrophoretic mobilities of analytes was investigated.