PHTHALOCYANINES SUBSTITUTED WITH CROWN-ETHERS THROUGH SULFANYL BRIDGES

MUSLUOGLU E., BEKAROGLU O.

JOURNAL OF CHEMICAL RESEARCH, no.11, pp.420-421, 1994 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: Issue: 11
  • Publication Date: 1994
  • Journal Name: JOURNAL OF CHEMICAL RESEARCH
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Metadex
  • Page Numbers: pp.420-421
  • Istanbul Technical University Affiliated: No

Abstract

Metal-free and metal phthalocyanines (M = Ni, Co, Cu, Zn, Pb or Sn(IV)Cl2) substituted with four benzo-15-crown-5 units through sulfanyl bridges have been synthesized from a new phthalonitrile derivative, viz. 1-{[(benzo-15-crown-5)]-4'-yl]thia}-3,4-dicyanobenzene; dagger the soluble products have been evaluated for electrical conductivity, alkali metal extraction and complexation with Pd(II) through sulfanyl bridges.