Versatile Postmodification of Conjugated Microporous Polymers Using Thiol-yne Chemistry

Kiskan B., WEBER J.

ACS MACRO LETTERS, vol.1, no.1, pp.37-40, 2012 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1 Issue: 1
  • Publication Date: 2012
  • Doi Number: 10.1021/mz200060z
  • Journal Name: ACS MACRO LETTERS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.37-40
  • Istanbul Technical University Affiliated: Yes


Radical thiol-yne chemistry is used for the modification of microporous networks with aliphatic alcohols. The degree of functionalization can be tuned by varying the reacted amount of thiol. Porosity analysis indicates that the microporosity can be preserved within a certain range, however, a decrease in pore size is observed.