Versatile Postmodification of Conjugated Microporous Polymers Using Thiol-yne Chemistry


Kiskan B. , WEBER J.

ACS MACRO LETTERS, vol.1, no.1, pp.37-40, 2012 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1 Issue: 1
  • Publication Date: 2012
  • Doi Number: 10.1021/mz200060z
  • Title of Journal : ACS MACRO LETTERS
  • Page Numbers: pp.37-40

Abstract

Radical thiol-yne chemistry is used for the modification of microporous networks with aliphatic alcohols. The degree of functionalization can be tuned by varying the reacted amount of thiol. Porosity analysis indicates that the microporosity can be preserved within a certain range, however, a decrease in pore size is observed.