Versatile Postmodification of Conjugated Microporous Polymers Using Thiol-yne Chemistry


Kiskan B. , WEBER J.

ACS MACRO LETTERS, cilt.1, ss.37-40, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 1 Konu: 1
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1021/mz200060z
  • Dergi Adı: ACS MACRO LETTERS
  • Sayfa Sayıları: ss.37-40

Özet

Radical thiol-yne chemistry is used for the modification of microporous networks with aliphatic alcohols. The degree of functionalization can be tuned by varying the reacted amount of thiol. Porosity analysis indicates that the microporosity can be preserved within a certain range, however, a decrease in pore size is observed.