Versatile Postmodification of Conjugated Microporous Polymers Using Thiol-yne Chemistry

Kiskan B., WEBER J.

ACS MACRO LETTERS, cilt.1, sa.1, ss.37-40, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1 Sayı: 1
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1021/mz200060z
  • Dergi Adı: ACS MACRO LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.37-40
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Radical thiol-yne chemistry is used for the modification of microporous networks with aliphatic alcohols. The degree of functionalization can be tuned by varying the reacted amount of thiol. Porosity analysis indicates that the microporosity can be preserved within a certain range, however, a decrease in pore size is observed.