Fluorimetric trace determination of cerium(III) with sodium triphosphate


Akseli A., Rakicioglu Y.

TALANTA, cilt.43, ss.1983-1988, 1996 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 43 Konu: 11
  • Basım Tarihi: 1996
  • Doi Numarası: 10.1016/0039-9140(96)01987-x
  • Dergi Adı: TALANTA
  • Sayfa Sayıları: ss.1983-1988

Özet

Sodium triphosphate acts as a specific reagent for enhancing the fluorescence intensity of cerium(III). The purpose of this study was to investigate the spectrofluorimetric determination of trace amounts of Ce(III) in sodium triphosphate solution. The excitation and emission wavelengths are 303.5 nm and 353 nm respectively. Optimum sodium triphosphate concentration is found to be 0.074 g l(-1) at room temperature. The fluorescence varies linearly with the concentration of cerium(III) in the range 0.001-45 mu g ml(-1). The detection limit is 9.4 x 10(-4) mu g ml(-1). The relative standard deviations for 30 mu g ml(-1) and 0.05 mu g ml(-1) Ce(III) in 0.074 g l(-1) sodium triphosphate solution are 1.1% and 0.72% respectively. Quenching effects of other lanthanides and some inorganic anions are described. This method is a direct and rapid analytical method for the determination of Ce(III) in rare earth mixtures and cerium concentrates.