A WATER-SOLUBLE POLY(METHYLPHENYLSILYLENE) DERIVATIVE AS A PHOTOINITIATOR OF RADICAL POLYMERIZATION OF HYDROPHILIC VINYL MONOMERS

KMINEK I., YAGCI Y., SCHNABEL W.

POLYMER BULLETIN, cilt.29, ss.277-282, 1992 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 29
  • Basım Tarihi: 1992
  • Doi Numarası: 10.1007/bf00944819
  • Dergi Adı: POLYMER BULLETIN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.277-282
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Radicals formed during photoscission of the pyridinium salt of partially chloromethylated poly(methylphenylsilylene) (Q-PMPSi) in aqueous solution are capable of initiating the polymerization of hydrophilic vinyl monomers, e.g. acrylic and methacrylic acid, acrylamide, 2-hydroxyethyl methacrylate and 1-vinyl-2-pyrrolidone. [GRAPHICS]