A WATER-SOLUBLE POLY(METHYLPHENYLSILYLENE) DERIVATIVE AS A PHOTOINITIATOR OF RADICAL POLYMERIZATION OF HYDROPHILIC VINYL MONOMERS


KMINEK I., YAGCI Y. , SCHNABEL W.

POLYMER BULLETIN, cilt.29, ss.277-282, 1992 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 29
  • Basım Tarihi: 1992
  • Doi Numarası: 10.1007/bf00944819
  • Dergi Adı: POLYMER BULLETIN
  • Sayfa Sayıları: ss.277-282

Özet

Radicals formed during photoscission of the pyridinium salt of partially chloromethylated poly(methylphenylsilylene) (Q-PMPSi) in aqueous solution are capable of initiating the polymerization of hydrophilic vinyl monomers, e.g. acrylic and methacrylic acid, acrylamide, 2-hydroxyethyl methacrylate and 1-vinyl-2-pyrrolidone. [GRAPHICS]