Synthesis of poly(t-butyl acrylate) macromer with vinyl ether functionality by metal-free anionic polymerization


Hızal G.

POLYMER, vol.37, no.3, pp.541-543, 1996 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 37 Issue: 3
  • Publication Date: 1996
  • Doi Number: 10.1016/0032-3861(96)82929-6
  • Title of Journal : POLYMER
  • Page Numbers: pp.541-543

Abstract

The anionic polymerization of t-butyl acrylate was achieved by using ethyl vinyl ether functionalized carbanionic initiator. In this way, poly(t-butyl acrylate) macromer with vinyl ether functionality was obtained. The macromer structure was characterized with the aid of H-1 nuclear magnetic resonance spectroscopy and gel permeation chromatography.