Thermally Curable Polyoxanorbornene by Ring Opening Metathesis Polymerization

TAŞDELEN M. A. , Durmaz H.

MACROMOLECULAR CHEMISTRY AND PHYSICS, cilt.212, sa.19, ss.2121-2126, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 212 Konu: 19
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1002/macp.201100258
  • Dergi Adı: MACROMOLECULAR CHEMISTRY AND PHYSICS
  • Sayfa Sayıları: ss.2121-2126

Özet

A novel norbornene monomer bearing a thermally curable benzoxazine group is synthesized and polymerized by ROMP using the Grubbs first-generation ruthenium catalyst. The (M) over bar (w) of the side-chain benzoxazine functionalized polyoxanorbornene can be up to 87 000 Da with unimodal molecular-weight distribution and narrow polydispersity between 1.18 and 1.65. Thermally activated ring-opening polymerization of benzoxazine moieties leads to the formation of highly cross-linked structures. The effects of molecular weight on the thermal ROP of polybenzoxazine precursors are examined.