The Synthesis of New Triazole-Linked Supramolecules Based on Bis-[1,3]-Naphthodioxocines

Özükanar Ö., Talinli N., Kumbaracı İ. V.

CHEMISTRYSELECT, vol.7, no.13, 2022 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 7 Issue: 13
  • Publication Date: 2022
  • Doi Number: 10.1002/slct.202200652
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier
  • Keywords: bis-naphto-1, 3-dioxocine linkers, macrocycles, molecular cage, supramolecular chemistry, triazole, MOLECULAR TWEEZERS, IN-VITRO, SYSTEM, TUBES, HOST, 1,2,3-TRIAZOLE, DERIVATIVES
  • Istanbul Technical University Affiliated: Yes


In this study, the synthesis of novel three molecular cages based on bis-structure of 8,16-methano-16H-dinaphtho[2,1-d: 1',2'-g][1,3]dioxocine (DNDO) is reported. The linkers between bis-DNDO structures are bearing both etheric structures and bis(1,2,3-triazole) moieties that are acting also as coordination ligands. The cavities of the molecular cages change depending of the position of dioxocine ring oxygens.