The Synthesis of New Triazole-Linked Supramolecules Based on Bis-[1,3]-Naphthodioxocines


Özükanar Ö., Talinli N., Kumbaracı İ. V.

CHEMISTRYSELECT, cilt.7, sa.13, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 7 Sayı: 13
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1002/slct.202200652
  • Dergi Adı: CHEMISTRYSELECT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier
  • Anahtar Kelimeler: bis-naphto-1, 3-dioxocine linkers, macrocycles, molecular cage, supramolecular chemistry, triazole, MOLECULAR TWEEZERS, IN-VITRO, SYSTEM, TUBES, HOST, 1,2,3-TRIAZOLE, DERIVATIVES
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

In this study, the synthesis of novel three molecular cages based on bis-structure of 8,16-methano-16H-dinaphtho[2,1-d: 1',2'-g][1,3]dioxocine (DNDO) is reported. The linkers between bis-DNDO structures are bearing both etheric structures and bis(1,2,3-triazole) moieties that are acting also as coordination ligands. The cavities of the molecular cages change depending of the position of dioxocine ring oxygens.