Methacryloyl-Functional Benzoxazine: Photopolymerization and Thermally Activated Polymerization

Jin L., Agag T., Yagci Y. , Ishida H.

MACROMOLECULES, cilt.44, sa.4, ss.767-772, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Konu: 4
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1021/ma102351a
  • Sayfa Sayıları: ss.767-772


A novel class of photopolymerizable benzoxazines has been developed. This class has been coined as methacryloyl-functional benzoxazines. It has been synthesized by the reaction of the new benzoxazine monomers: (3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methanol and methacryloyl chloride. The structure of the monomer has been confirmed by Fourier transform infrared spectroscopy (FTIR) and H-1 and C-13 nuclear magnetic resonance spectroscopy (NMR). Its photopolymerization has been successfully carried out with and without photoinitiator, while the thermally activated polymerization is compromised by low temperature degradation.