Block copolymer synthesis and chain extension from TEMPO-terminated chains formed by ultrasonic chain scission

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Atıf İçin Kopyala

Catalgil-Giz H. H., HEPUZER Y.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.77, sa.9, ss.1950-1953, 2000 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 77 Sayı: 9
• Basım Tarihi: 2000
• Doi Numarası: 10.1002/1097-4628(20000829)77:9<1950::aid-app10>3.0.co;2-j
• Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1950-1953
• İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Long poly(ethyl methacrylate) (M-n = 2,300,000) and polystyrene (M-n = 1,200,000) chains were subjected to ultrasonic scission in the presence of a radical scavenger, 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO). This procedure yielded polymers with lower molecular weights and TEMPO terminal units. Application of these polymers in stable radical mediated polymerization of styrene resulted in chain extension and block copolymers, depending on the precursor polymer. Block copolymer formation was evidenced by NMR measurement, and chain extension was shown by GPC analysis. (C) 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 1950-1953, 2000.