Directly and Indirectly Acting Photoinitiating Systems for Ring-Opening Polymerization of epsilon-Caprolactone

Bener S., Yilmaz G., Yağcı Y.

CHEMPHOTOCHEM, cilt.5, sa.12, ss.1089-1093, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 5 Sayı: 12
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1002/cptc.202100118
  • Dergi Adı: CHEMPHOTOCHEM
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Applied Science & Technology Source
  • Sayfa Sayıları: ss.1089-1093
  • Anahtar Kelimeler: activated monomer mechanism, caprolactone, cationic polymerization, polymerization, ring-opening polymerization, LONG-WAVELENGTH PHOTOSENSITIZER, CATIONIC-POLYMERIZATION, ACTIVATED MONOMER, METAL-COMPLEXES, COPOLYMERIZATION, MECHANISM, LACTONES
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Directly and indirectly acting photoinitiating systems for cationic ring opening polymerization (ROP) of epsilon-caprolactone (epsilon-CL) by using diphenyl iodonium salt (DPI) in the presence of benzyl alcohol were studied and mechanistic details were evaluated. In the direct system, the polymerization is initiated by a Bronsted acid formed upon UV irradiation of DPI. Polymerizations by indirectly acting photoinitiating systems proceeding via electron transfer reactions of photochemically formed electron donor radicals or excited states of polynuclear aromatic compounds with DPI were investigated. It was demonstrated that polymerizations proceed in a controlled manner by an activated monomer (AM) mechanism. Applicability of the photoinitiation to the other lactone monomers was validated on the example of delta- valerolactone (delta-VL).