THE PROPERTIES OF PALLADIUM ELECTRODES FOR ELECTROOXIDATION OF ETHYLENE-GLYCOL

DALBAY N., KADIRGAN F.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, cilt.296, sa.2, ss.559-569, 1990 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 296 Sayı: 2
  • Basım Tarihi: 1990
  • Doi Numarası: 10.1016/0022-0728(90)87272-l
  • Dergi Adı: JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.559-569
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

In order to interpret the electrocatalytic properties of palladium for the oxidation of ethylene glycol, a mechanistic investigation was carried out in alkaline medium. The kinetic parameters, estimated from electrochemical data, suggest a one electron step to be rate determining, and the rate of the reaction depends directly on the pH.