THE PROPERTIES OF PALLADIUM ELECTRODES FOR ELECTROOXIDATION OF ETHYLENE-GLYCOL

DALBAY, N; KADIRGAN, Figen

doi:10.1016/0022-0728(90)87272-l

THE PROPERTIES OF PALLADIUM ELECTRODES FOR ELECTROOXIDATION OF ETHYLENE-GLYCOL

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DALBAY N., KADIRGAN F.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol.296, no.2, pp.559-569, 1990 (SCI-Expanded)

Publication Type: Article / Article
Volume: 296 Issue: 2
Publication Date: 1990
Doi Number: 10.1016/0022-0728(90)87272-l
Journal Name: JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.559-569
Istanbul Technical University Affiliated: No

Abstract

In order to interpret the electrocatalytic properties of palladium for the oxidation of ethylene glycol, a mechanistic investigation was carried out in alkaline medium. The kinetic parameters, estimated from electrochemical data, suggest a one electron step to be rate determining, and the rate of the reaction depends directly on the pH.