Allyloxy isoquinolinium salts as initiators for cationic polymerization

ATMACA L., ONEN A., Yagci Y.

EUROPEAN POLYMER JOURNAL, cilt.37, sa.4, ss.677-682, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 37 Konu: 4
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1016/s0014-3057(00)00160-9
  • Sayfa Sayıları: ss.677-682


2-Propenyloxy isoquinolinium hexafluoroantimonate and 2-methyl-2-propenyloxy isoquinolinium hexafluoroantimonate were synthesized and characterized. Their capability to act as initiator and co-initiator for the cationic polymerization of cyclohexene oxide (CHO) was examined. Both thermally and photochemically latent effectiveness of these salts in promoting polymerization of CHO at 70 degreesC and lambda = 350 nm, respectively was investigated. The accelearating effect of thermal and photochemical radical sources were also demonstrated. The contribution of electron transfer and addition-fragmentation mechanisms was discussed. (C) 2001 Elsevier Science Ltd. All rights reserved.