Synthesis and characterization of a new 2,2 '-azoquinoxaline and its complexes with platinum and palladium

Gursoy S., Kocak M., Bekaroglu O.

MONATSHEFTE FUR CHEMIE, vol.131, no.2, pp.181-185, 2000 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 131 Issue: 2
  • Publication Date: 2000
  • Doi Number: 10.1007/pl00010304
  • Journal Name: MONATSHEFTE FUR CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.181-185
  • Istanbul Technical University Affiliated: Yes

Abstract

Platinum and palladium dichlorides react readily with 2,2'-azoquinoxaline to give the di-mu-chloro-2,2'-azobis-(7,7'-bis-benzoyl-quinoxaline) diplatinum(II) and dipalladium(II) complexes. These crystalline complexes exhibit both metal-carbon binding and coordinate metal-nitrogene binding to azoquinoxaline.