Synthesis of aromatic poly(ether ketone)s with ferrocene units in the main chain


Tunca U.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.253, ss.89-97, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 253
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1002/apmc.1997.052530107
  • Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Sayfa Sayıları: ss.89-97

Özet

Aromatic poly(ether ketone)s with ferrocene units in the main chain were prepared by direct polycondensation of 1,1'-ferrocenedicarboxylic acid with diphenyl ether or 1,4-diphenoxybenzene using various catalysts such as trifluoromethanesulfonic acid (triflic acid), a combination of methanesulfonic acid/P2O5 (Eaten's reagent) or a combination of triflic acid/P2O5. Polycondensations at room temperature for 24 h gave poly(arylene ether ketone)s with inherent viscosities up to 40 mL g(-1). Monoacylation of diphenyl ether with ferrocenecarboxylic acid was studied in detail in order to show the efficiency of polymer formation employing Eaten's reagent as catalyst and solvent.