Design of high-toughness polyacrylamide hydrogels by hydrophobic modification

Abdurrahmanoglu S., CAN V., Okay O.

POLYMER, vol.50, no.23, pp.5449-5455, 2009 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 50 Issue: 23
  • Publication Date: 2009
  • Doi Number: 10.1016/j.polymer.2009.09.042
  • Journal Name: POLYMER
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.5449-5455
  • Istanbul Technical University Affiliated: Yes


Polyacrylamide (PAAm) hydrogels possessing a very large extensibility at break have been prepared via micellar crosslinking copolymerization of acrylamide monomer and N,N'-methylenebis(acrylamide) crosslinker in the presence of hydrophobic comonomers. N-butyl-, N-hexyl-, N-octyl-, and N,N-dihexylacrylamides were used as the hydrophobes in the hydrogel preparation. Incorporation of hydrophobes with an alkyl chain length x > 4 results in an increase in the loss factor tan 6 of hydrogels due to the formation of temporary junction zones inside the gel network. The number N-H of the hydrophobes per hydrophobic block together with the alkyl chain length x of the pendant hydrophobic group were used to tune the loss factor of the hydrogels over two orders of magnitude. Tensile mechanical measurements show that increasing N-H or x also increases the degree of toughness of PAAm hydrogels. Keeping constant the hydrophobe level (20 mol%) at an alkyl chain length x=6, increasing N-H from 9 to 30 increased the elongation ratio at break from 125 to 250%. Hydrogels exhibiting a high toughness, i.e., about 300% elongation ratio at break were obtained by modification of PAAm network chains with 10 mol% N-octylacrylamide. (C) 2009 Elsevier Ltd. All rights reserved.