SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING beta-THIOETHER APPENDED [(bpy)(2)RuCl2]


AYTAN KILIÇARSLAN F., ERDOĞMUŞ A., YALÇIN S. S. , Gül A.

SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI, cilt.36, ss.487-499, 2018 (ESCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 36 Konu: 2
  • Basım Tarihi: 2018
  • Dergi Adı: SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI
  • Sayfa Sayıları: ss.487-499

Özet

In this study, (ethylsulfanyl) porphyrazines have been modified with one peripheral ruthenium bipyridine groups. These compounds possess (bpy)(2)Ru-II moieties directly attached to the beta position in the (ethylsulfanyl) porphyrazines through thioether chelation. The new compounds have been characterized by elemental analysis, FT-IR, H-1-NMR spectroscopy and mass spectra. The spectral properties such as electronic spectra, aggregation and fluorescence of compounds have been studied in THF. Insertion of (bpy)(2)Ru-II moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.