SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING beta-THIOETHER APPENDED [(bpy)(2)RuCl2]


AYTAN KILIÇARSLAN F., ERDOĞMUŞ A., YALÇIN S. S. , Gül A.

SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI, vol.36, no.2, pp.487-499, 2018 (Journal Indexed in ESCI) identifier

  • Publication Type: Article / Article
  • Volume: 36 Issue: 2
  • Publication Date: 2018
  • Title of Journal : SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI
  • Page Numbers: pp.487-499

Abstract

In this study, (ethylsulfanyl) porphyrazines have been modified with one peripheral ruthenium bipyridine groups. These compounds possess (bpy)(2)Ru-II moieties directly attached to the beta position in the (ethylsulfanyl) porphyrazines through thioether chelation. The new compounds have been characterized by elemental analysis, FT-IR, H-1-NMR spectroscopy and mass spectra. The spectral properties such as electronic spectra, aggregation and fluorescence of compounds have been studied in THF. Insertion of (bpy)(2)Ru-II moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.