Utility of atom transfer radical polymerization for the preparation of poly(methyl methacrylate) beads in an aqueous suspension

Bicak, N; Gazi, M; Tunca, Ümit; Kucukkaya, I

doi:10.1002/pola.11093

Utility of atom transfer radical polymerization for the preparation of poly(methyl methacrylate) beads in an aqueous suspension

Atıf İçin Kopyala

Bicak N., Gazi M., Tunca U., Kucukkaya I.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.42, sa.6, ss.1362-1367, 2004 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 42 Sayı: 6
Basım Tarihi: 2004
Doi Numarası: 10.1002/pola.11093
Dergi Adı: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1362-1367
İstanbul Teknik Üniversitesi Adresli: Evet

Özet

The copper-mediated atom transfer radical polymerization of methyl methacrylate proceeds with first-order kinetics and controlled chain (300-600 mum) in growth to yield nearly spherical bead polymers aqueous suspensions when hexylated triethylenetetramine and poly(vinyl pyrrolidone) are used as the ligand and stabilizer, respectively.