Utility of atom transfer radical polymerization for the preparation of poly(methyl methacrylate) beads in an aqueous suspension


Bicak N., Gazi M., Tunca U. , Kucukkaya I.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.42, sa.6, ss.1362-1367, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Konu: 6
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1002/pola.11093
  • Dergi Adı: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
  • Sayfa Sayıları: ss.1362-1367

Özet

The copper-mediated atom transfer radical polymerization of methyl methacrylate proceeds with first-order kinetics and controlled chain (300-600 mum) in growth to yield nearly spherical bead polymers aqueous suspensions when hexylated triethylenetetramine and poly(vinyl pyrrolidone) are used as the ligand and stabilizer, respectively.