Synthesis and characterization of novel octakis(2'-aminophenoxy and 2'-aminophenylsulfanyl)-substituted metallophthalocyanines


Kandaz M., Bekaroglu O.

CHEMISCHE BERICHTE-RECUEIL, vol.130, no.12, pp.1833-1836, 1997 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 130 Issue: 12
  • Publication Date: 1997
  • Doi Number: 10.1002/cber.19971301220
  • Title of Journal : CHEMISCHE BERICHTE-RECUEIL
  • Page Numbers: pp.1833-1836

Abstract

Novel phthalocyanines (M = Ni, Zn, Co) bearing eight 2'- aminophenoxy and 2'-amino phenylsulfanyl substituents on peripheral positions have been prepared starting from 4,5-bis(2'-aminophenoxy)-1, 2-dicyanobenzene or 4,5-bis(2'-aminophenyl sulfanyl)-1,2-dicyanobenzene and the corresponding anhydrous metal salts [NiCl2, Zn(O2CMe)(2), CoCI2]. Complexation of octakis(2'-amino phenylsulfanyl)-substituted metallo phthalocyanines (2b, 3b and 4b) with Pd-II to form the pentanuclear product was accomplished from their mixtures.