Synthesis and characterization of novel octakis(2'-aminophenoxy and 2'-aminophenylsulfanyl)-substituted metallophthalocyanines

Kandaz M., Bekaroglu O.

CHEMISCHE BERICHTE-RECUEIL, cilt.130, sa.12, ss.1833-1836, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 130 Sayı: 12
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1002/cber.19971301220
  • Dergi Adı: CHEMISCHE BERICHTE-RECUEIL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1833-1836
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

Novel phthalocyanines (M = Ni, Zn, Co) bearing eight 2'- aminophenoxy and 2'-amino phenylsulfanyl substituents on peripheral positions have been prepared starting from 4,5-bis(2'-aminophenoxy)-1, 2-dicyanobenzene or 4,5-bis(2'-aminophenyl sulfanyl)-1,2-dicyanobenzene and the corresponding anhydrous metal salts [NiCl2, Zn(O2CMe)(2), CoCI2]. Complexation of octakis(2'-amino phenylsulfanyl)-substituted metallo phthalocyanines (2b, 3b and 4b) with Pd-II to form the pentanuclear product was accomplished from their mixtures.