Synthesis and characterisation of unsymmetrical porphyrazines containing bis(hydroxyethylthio) substituents

Kalkan A., Bayir Z.

MONATSHEFTE FUR CHEMIE, vol.134, no.12, pp.1555-1560, 2003 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 134 Issue: 12
  • Publication Date: 2003
  • Doi Number: 10.1007/s00706-003-0074-5
  • Journal Name: MONATSHEFTE FUR CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1555-1560
  • Istanbul Technical University Affiliated: Yes

Abstract

Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, H-1 NMR, UV-Vis, and mass spectra.