Synthesis and characterisation of unsymmetrical porphyrazines containing bis(hydroxyethylthio) substituents


Kalkan A., Bayir Z.

MONATSHEFTE FUR CHEMIE, cilt.134, sa.12, ss.1555-1560, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 134 Konu: 12
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1007/s00706-003-0074-5
  • Dergi Adı: MONATSHEFTE FUR CHEMIE
  • Sayfa Sayıları: ss.1555-1560

Özet

Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, H-1 NMR, UV-Vis, and mass spectra.