Visible light-induced free radical promoted cationic polymerization using organotellurium compounds


Kaya K. , Seba M., Fujita T., Yamago S., Yagci Y.

POLYMER CHEMISTRY, cilt.9, sa.48, ss.5639-5643, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 9 Konu: 48
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1039/c8py01380b
  • Dergi Adı: POLYMER CHEMISTRY
  • Sayfa Sayıları: ss.5639-5643

Özet

Organotellurium-mediated polymerization of cyclohexene oxide (CHO), isobutyl vinyl ether (IBVE) and N-vinylcarbazole (NVC) in the presence of diphenyliodonium hexafluorophosphate (DPI) was accomplished under visible light and sunlight. The chain-transfer agent (CTA) ethyl 2-methyl-2-methyltellanylpropionate (EMPTeMe) and poly(methyl methacrylate) with an organotellurium group at the chain end (PMMATeMe) were used as photoinitiators.