A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Atsay A. , NAR I. , Hamuryudan E. , KOCAK M. , Guel A.

CHEMISTRYSELECT, cilt.2, sa.28, ss.9233-9235, 2017 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2 Konu: 28
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1002/slct.201702078
  • Sayfa Sayıları: ss.9233-9235


Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(alpha) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(beta) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.