COORDINATION OF COPPER AND SILVER BY [CO2(MU-C2(CH2SCH2CH2)2S)(CO)6]

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DEMIRHAN F., IRISLI S., SALEK S., SENTURK O. S., WENT M., JEFFERY J.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.453, no.2, 1993 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 453 Issue: 2
• Publication Date: 1993
• Doi Number: 10.1016/0022-328x(93)83134-h
• Journal Name: JOURNAL OF ORGANOMETALLIC CHEMISTRY
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Istanbul Technical University Affiliated: No

Abstract

The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitution.