COORDINATION OF COPPER AND SILVER BY [CO2(MU-C2(CH2SCH2CH2)2S)(CO)6]


DEMIRHAN F., IRISLI S., SALEK S., SENTURK O. S. , WENT M., JEFFERY J.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.453, no.2, 1993 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 453 Issue: 2
  • Publication Date: 1993
  • Doi Number: 10.1016/0022-328x(93)83134-h
  • Title of Journal : JOURNAL OF ORGANOMETALLIC CHEMISTRY

Abstract

The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitution.