Novel antifouling and antibacterial polyethersulfone membrane prepared by embedding nitrogen-doped carbon dots for efficient salt and dye rejection

Koulivand H., Shahbazi A., Vatanpour Sargheın V., Rahmandoost M.

MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, cilt.111, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 111
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.msec.2020.110787
  • Dergi Adı: MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Agricultural & Environmental Science Database, Biotechnology Research Abstracts, Communication Abstracts, Compendex, EMBASE, INSPEC, MEDLINE, Metadex, Civil Engineering Abstracts
  • Anahtar Kelimeler: Nanofiltration, Carbon dots, Antifouling, Antibacterial, Salt rejection, ONE-STEP SYNTHESIS, QUANTUM DOTS, ULTRAFILTRATION MEMBRANE, NANOFILTRATION MEMBRANES, HIGH-FLUX, ENHANCEMENT, FABRICATION, POLYAMIDE, BACTERIA, REMOVAL
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

Novel antifouling and antibacterial nanofiltration membranes were prepared by addition of nitrogen-doped carbon dots (NCDs) to the polyethersulfone (PES). The antibacterial NCDs were successfully fabricated using hydrothermal technique and then were characterized using photoluminescence (PL) spectra, FTIR, XRD, and dynamic light scattering (DLS). The resulted nanoparticles were introduced to PES through the phase separation method. The effect of adding NCDs into the PES membrane, as a novel nanofiller was studied in terms of surface and cross-sectional morphology, hydrophilicity, porosity, permeation, fouling resistance, antibacterial properties, and nanofiltration performance. All the NCD-blended membranes exhibited better performance compared to the bare PES. The water flux was significantly increased from 16.5 kg/m(2)h for the bare PES to 44.6 kg/m(2)h for the 0.50 wt% NCD-blended membrane. The 0.50 wt% of NCD-blended PES membrane also showed the best antifouling properties, with a flux recovery ratio (FRR) of 73.1%. The retention sequence of the salts was Na2SO4 (80.3%) > MgSO4 (63.5%) > NaCl (20.7%), showing the common behavior of the negative charge nanofiltration membranes. The antibacterial assessment showed a zone of inhibition for both Gram-negative and Grampositive bacteria in disks membranes containing higher than 0.10 wt% of NCD concentrations. The results offer NCD-blended membranes as a high potential hydrophilic and antibacterial nanofillers.