Synthetic Strategies to Combine High Performance Benzoxazine Thermosets with Polymers

Kışkan B., YAGCI Y.

18th World Forum on Advanced Polymeric Materials, Siegen, Almanya, 7 - 10 Nisan 2010, cilt.298, ss.145-153 identifier identifier

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Cilt numarası: 298
  • Doi Numarası: 10.1002/masy.201000043
  • Basıldığı Şehir: Siegen
  • Basıldığı Ülke: Almanya
  • Sayfa Sayıları: ss.145-153
  • Anahtar Kelimeler: benzoxazine, cross-linking, main and side chain functional polymers, thermoset, FIBER-REINFORCED POLYBENZOXAZINE, MAIN-CHAIN, CLICK CHEMISTRY, THERMAL POLYMERIZATION, RADICAL POLYMERIZATION, MONOMERS, POLYSTYRENE, IMPROVEMENT, COMPOSITES, MOIETIES
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Polybenzoxazines are newly developed thermosetting polymers exhibiting versatility in a wide range of applications including electronics and aerospace industries. They exhibit highly competitive combination of properties compare to the conventional thermosets. In this paper we present synthetic strategies to incorporate thermally curable benzoxazine functions into polymers as main and side chain groups in order to further improve various properties. The strategies successfully employed include monomer synthesis, macromonomer method, poly-condensation, oxidative polymerization, photo-polymerization, click chemistry and hydrosilylation processes. In the case of macromononomer method functional initiators were used in various controlled/living polymerizations to give polymers with benzoxazine end groups. The thermal curing behaviors of the obtained polymers were also demonstrated.