Synthesis and characterization of conducting block copolymers of thiophene-ended polystyrene with polypyrrole

Alkan S., TOPPARE L., HEPUZER Y., YAGCI Y.

SYNTHETIC METALS, cilt.119, ss.133-134, 2001 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 119
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1016/s0379-6779(00)01402-8
  • Dergi Adı: SYNTHETIC METALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.133-134
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

4,4' Azobis 4-cyano3-thiophenemethyl pentanate (ACTMP) was synthesized from 3-Thiophenemethanol and 4,4'-Azobis (4-cyanopentanoyl chloride). ACTMP was further used in the synthesis of polystyrene with thiophene terminal groups (TPSt) at both ends. Conducting block copolymers of TPSt and pyrrole (TPSt/PPy) were electrochemically prepared using several supporting electrolytes. Characterization of these block copolymers were performed.