Synthesis and properties of octakis(octylthio)porphyrazinatoiron derivatives


Hasanov B., Gul A.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.31, sa.4, ss.673-680, 2001 (SCI-Expanded) identifier identifier

Özet

Chlorooetakis(octylthio)porphyrazinatoiron(III) (FePzCl) was prepared by the reaction of metal-free porphyrazine with iron(II) acetate and further treatment with HCl solution. The monomeric bisaxial complex FePz(PY)(2) as well as the bridged complex [FePz(pyz)](n) were formed as stable complexes by reacting FePzCl with pyridine or pyrazine, respectively. These complexes were characterized by elemental analysis and spectroscopic methods.