Synthesis and properties of octakis(octylthio)porphyrazinatoiron derivatives


Hasanov B., Gul A.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.31, ss.673-680, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 31 Konu: 4
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1081/sim-100104795
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Sayfa Sayıları: ss.673-680

Özet

Chlorooetakis(octylthio)porphyrazinatoiron(III) (FePzCl) was prepared by the reaction of metal-free porphyrazine with iron(II) acetate and further treatment with HCl solution. The monomeric bisaxial complex FePz(PY)(2) as well as the bridged complex [FePz(pyz)](n) were formed as stable complexes by reacting FePzCl with pyridine or pyrazine, respectively. These complexes were characterized by elemental analysis and spectroscopic methods.