Phthalocyanines with rigid carboxylic acid containing pendant arms

Kalkan A., Bayir Z.

POLYHEDRON, cilt.25, sa.1, ss.39-42, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 25 Sayı: 1
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1016/j.poly.2005.06.056
  • Dergi Adı: POLYHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.39-42
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Metal-free and metallophthalocyanines (Zn, Co) substituted with four carboxybiphenyloxy groups on the peripheral positions were prepared from 4-(4'-carboxybiphenyloxy)phthalonitrile. Esterification of all of the biphenylcarboxylic acid groups of metal-free phthalocyanine with hexanol afforded 2,9,16,23-tetrakis(4'-carbhexyloxybiphenyloxy) phthalocyanine. These new compounds have been characterised by H-1 NMR, C-13 NMR, FT-IR, UV-Vis and mass spectroscopies. (c) 2005 Elsevier Ltd. All rights reserved.