Photoinduced free radical promoted cationic polymerization 40 years after its discovery


TAŞDELEN M. A. , Lalevee J., Yağcı Y.

POLYMER CHEMISTRY, cilt.11, sa.6, ss.1111-1121, 2020 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 11 Konu: 6
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/c9py01903k
  • Dergi Adı: POLYMER CHEMISTRY
  • Sayfa Sayıları: ss.1111-1121

Özet

This perspective article is prepared in the memory of Anthony Ledwith who discovered Free Radical Promoted Cationic Polymerization (FRPCP) as a versatile photoinitiating system for cationic polymerization about four decades ago. Mechanistically, distinct modes for the photochemical formation of electron donor radicals in the UV, Vis and NIR range that can be oxidized to reactive cations to initiate the cationic polymerization of oxiranes and vinyl monomers are discussed. The dual polymerization strategies that have been applied to combine FRPCP with the other modes of polymerization processes are presented.