Preconcentration of phenols by adsorption on organo-clay followed by capillary electrophoretic determination


ERIM F., Alemdar I.

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, cilt.361, sa.5, ss.455-458, 1998 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 361 Sayı: 5
  • Basım Tarihi: 1998
  • Doi Numarası: 10.1007/s002160050925
  • Dergi Adı: FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.455-458
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

The organo-clay adsorbent used was prepared by modification of montmorillonite from Kursunlu, Turkey with the cationic surfactant cetyltrimethlyammonium bromide. The modification process involves replacing the inorganic exchange cations of the clay by organic cations containing long chain alkyl groups. The retention of phenolic compounds from aqueous solution on the organoclay was studied. The analytes are quantitatively retained on the proposed adsorbent at pH 7 and recovered by elution with ethanol. The determination of phenols was performed by capillary electrophoresis.