Synthesis and electrochemical and spectroelectrochemical characterization of chloromanganese(III) phthalocyanines


Özçeşmeci M. , NAR I. , Hamuryudan E.

TURKISH JOURNAL OF CHEMISTRY, cilt.38, ss.1064-1072, 2014 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 38 Konu: 6
  • Basım Tarihi: 2014
  • Doi Numarası: 10.3906/kim-1405-43
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.1064-1072

Özet

The synthesis of novel, symmetrical, tetrasubstituted manganese phthalocyanine complexes bearing 4 hexylthio, 2',3',4',5',6'-pentafluorobenzyloxy, 2',3',5',6'-tetrafluoro-4'-hexylthio-benzyloxy, and 2',3',5',6'-tetrafluoro-4'pentoxy-benzyloxy units is reported. The new compounds have been characterized by using elemental analyses and UV-Vis, FT-IR, and mass spectroscopic data. The electrochemical properties of the manganese phthalocyanine complexes were investigated by cyclic and square wave voltammetry and the nature of the observed redox processes was studied by spectroelectrochemistry.