Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio]tetrathiafulvalene and related materials

Ozturk, Turan; SAYGILI, N; OZKARA, S; PILKINGTON, M; RICE, CR; TRANTER, DA; TURKSOY, F; WALLIS, JD

doi:10.1039/b007660k

Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio]tetrathiafulvalene and related materials

Atıf İçin Kopyala

Ozturk T., SAYGILI N., OZKARA S., PILKINGTON M., RICE C., TRANTER D., ...Daha Fazla

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, sa.4, ss.407-414, 2001 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 2001
Doi Numarası: 10.1039/b007660k
Dergi Adı: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.407-414
İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

The synthesis of four novel organosulfur donors carrying two or more hydroxymethyl groups are described. TTF nuclei are fused to 1,4-dithiepine and/or 1,4-dithiine rings and in two cases both outer rings carry functionality capable of introducing hydrogen bonding; for the two chiral organosulfur donor molecules both racemic and enantiopure forms are prepared.