Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio]tetrathiafulvalene and related materials


Ozturk T. , SAYGILI N., OZKARA S., PILKINGTON M., RICE C., TRANTER D., ...More

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, no.4, pp.407-414, 2001 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 2001
  • Doi Number: 10.1039/b007660k
  • Title of Journal : JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
  • Page Numbers: pp.407-414

Abstract

The synthesis of four novel organosulfur donors carrying two or more hydroxymethyl groups are described. TTF nuclei are fused to 1,4-dithiepine and/or 1,4-dithiine rings and in two cases both outer rings carry functionality capable of introducing hydrogen bonding; for the two chiral organosulfur donor molecules both racemic and enantiopure forms are prepared.