N-Acyl Dibenzazepine Chemistry as Versatile Approach for Photoreversible Thiol-Ene Networks


Bener S., Aydogan C., Yağcı Y.

MACROMOLECULAR RAPID COMMUNICATIONS, vol.41, no.19, 2020 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 41 Issue: 19
  • Publication Date: 2020
  • Doi Number: 10.1002/marc.202000369
  • Journal Name: MACROMOLECULAR RAPID COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Agricultural & Environmental Science Database, Applied Science & Technology Source, Chimica, Communication Abstracts, Compendex, EMBASE, INSPEC, MEDLINE, Metadex, Civil Engineering Abstracts
  • Istanbul Technical University Affiliated: Yes

Abstract

It is herein reported that a facile application ofN-acyl dibenzazepine (ADBA) photochemistry for preparing photoreversible ADBA based thiol-ene networks. Crosslinking of the ADBA thiol-ene networks is successfully achieved by UV induced dimerization of ADBA groups at wavelengths above 300 nm while a subsequent deep UV exposure (lambda = 250 nm) results in a well-defined cleavage of the crosslinks. The photochemical bonding and cleavage of the process has been determined and studied in detail by spectroscopic measurements.