SEPARATION OF NICKEL AND IRON FROM LATERITIC ORE USING A DIGESTION - ROASTING - LEACHING - PRECIPITATION PROCESS


Basturkcu H., Acarkan N.

PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING, cilt.52, sa.2, ss.564-574, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 52 Sayı: 2
  • Basım Tarihi: 2016
  • Doi Numarası: 10.5277/ppmp160204
  • Dergi Adı: PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.564-574
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

This paper investigates extraction of nickel and iron from a lateritic nickel ore from the Caldag region of Manisa in Turkey. The ore sample contains 1.2% Ni, 24.77% Fe and 0.062% Co. The process applied includes digestion with 40 wt-% sulfuric acid at 200 degrees C for 60 min, roasting at 700 degrees C for 15 min, leaching with water for 30 min at 1: 5 solid/liquid ratio (by weight) and precipitation of the remaining iron at pH 3 and 60 degrees C. In order to improve nickel and cobalt extractions using the digestion-roasting-leaching-precipitation process (DRLP), Na2SO4 addition in the roasting stage was examined. Under the optimum conditions and in the presence of Na2SO4, 86.2% Ni and 94.2% Co extractions were obtained with almost zero iron content. As a result, 2.07 g dm(-3) Ni, 0.12 g dm(-3) Co and 0.05 g dm(-3) Fe could be achieved in the pregnant leach solution within nearly 2.5 hours.