Functionalised organosulfur donor molecules: synthesis of racemic hydroxymethyl-, alkoxymethyl- and dialkoxymethyl-bis(ethylenedithio)tetrathiafulvalenes

Saygili, N; BROWN, RJ; DAY, P; HOELZL, R; KATHIRGAMANATHAN, P; MAGEEAN, ER; Ozturk, Turan; PILKINGTON, M; QAYYUM, MMB; TURNER, SS; VORWERG, L; WALLIS, JD

doi:10.1016/s0040-4020(01)00432-x

Functionalised organosulfur donor molecules: synthesis of racemic hydroxymethyl-, alkoxymethyl- and dialkoxymethyl-bis(ethylenedithio)tetrathiafulvalenes

Copy For Citation

Saygili N., BROWN R., DAY P., HOELZL R., KATHIRGAMANATHAN P., MAGEEAN E., ...More

TETRAHEDRON, vol.57, no.23, pp.5015-5026, 2001 (SCI-Expanded)

Publication Type: Article / Article
Volume: 57 Issue: 23
Publication Date: 2001
Doi Number: 10.1016/s0040-4020(01)00432-x
Journal Name: TETRAHEDRON
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.5015-5026
Istanbul Technical University Affiliated: No

Abstract

Short synthetic routes to racemic derivatives of bis(ethylenedithio)tetrathiafulvalene carrying one hydroxymethyl (HMET), alkoxymethyl or dialkoxymethyl side chain are reported along with cyclic voltammetry measurements and conversion of HMET to (2:1) radical cation salts. (C) 2001 Elsevier Science Ltd. All rights reserved.