Functionalised organosulfur donor molecules: synthesis of racemic hydroxymethyl-, alkoxymethyl- and dialkoxymethyl-bis(ethylenedithio)tetrathiafulvalenes


Saygili N., BROWN R., DAY P., HOELZL R., KATHIRGAMANATHAN P., MAGEEAN E., ...More

TETRAHEDRON, vol.57, no.23, pp.5015-5026, 2001 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 57 Issue: 23
  • Publication Date: 2001
  • Doi Number: 10.1016/s0040-4020(01)00432-x
  • Journal Name: TETRAHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.5015-5026
  • Istanbul Technical University Affiliated: No

Abstract

Short synthetic routes to racemic derivatives of bis(ethylenedithio)tetrathiafulvalene carrying one hydroxymethyl (HMET), alkoxymethyl or dialkoxymethyl side chain are reported along with cyclic voltammetry measurements and conversion of HMET to (2:1) radical cation salts. (C) 2001 Elsevier Science Ltd. All rights reserved.