High Capacity and High Density Functional Conductive Polymer and SiO Anode for High-Energy Lithium-Ion Batteries

Zhao H., Yuca N., Zheng Z., Fu Y., Battaglia V. S., Abdelbast G., ...Daha Fazla

ACS APPLIED MATERIALS & INTERFACES, cilt.7, sa.1, ss.862-866, 2015 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 7 Sayı: 1
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1021/am507376f
  • Dergi Adı: ACS APPLIED MATERIALS & INTERFACES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.862-866
  • Anahtar Kelimeler: calendering, conductive polymer binder, lithium-ion battery, silicon monoxide, SENSITIZED SOLAR-CELL, SILICA NANOPARTICLES, NEGATIVE ELECTRODE, HYBRID FILMS, DESIGN, BINDER, LI, PERFORMANCE, SIMULATION, LIMN2O4
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

High capacity and high density functional conductive polymer binder/SiO electrodes are fabricated and calendered to various porosities. The effect of calendering is investigated in the reduction of thickness and porosity, as well as the increase of density. SiO particle size remains unchanged after calendering. When compressed to an appropriate density, an improved cycling performance and increased energy density are shown compared to the uncalendered electrode and overcalendered electrode. The calendered electrode has a high-density of similar to 1.2 g/cm(3). A high loading electrode with an areal capacity of similar to 3.5 mAh/cm(2) at a C/10 rate is achieved using functional conductive polymer binder and simple and effective calendering method.